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- By
- The USF Nutrient Group (K. Fanning, Y. Serebrennikova, R. Masserini, H.
Rutherford, and R. Conroy)
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- Nitrate & Nitrite: Sulfanilamide (SAN) + naphthyl-ethylaminediamine
(NED)
- Phosphate & Silica: Ammonium
Molybdate + reducing agents (hydrazine sulfate, stannous chloride)
- Ammonia: alkaline phenol + sodium hypochlorite (bleach)
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12
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- Change (µM)
- Upper Phosphate ~0.4 (or
~25% increase)
- Deep Phosphate ~0.0
- Upper Nitrate ~6.0 (or ~30% increase)
- Deep Nitrate ~0.0
- Upper Silica ~10 (or ~20% increase)
- Deep Silica
~0
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13
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- Very high ammonia concentrations on 103 cruise: > 4 micromolar!
- Ammonia concentrations decline in upper water column Consumption? Nitrification?
- Deep ammonia concentrations remain at zero.
- Ammonia decline demonstrated best by integrating ammonia profiles at
each station down to depth of zero ammonia: standing stock of ammonia.
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15
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- Nitrate, phosphate, and silica increased 20-40% in the upper water
column between cruises.
- Ammonia declined strongly (~60%) in the upper water column between
cruises.
- Very high standing stock of ammonia in Marguerite Bay
- ~500 µmol/m2
- possibly drifted to southwest during cruise 103
- declined ~3-fold between cruises
- Nutrient remineralization (nitrification) possible but difficult to
explain quantitatively
- No attempt to correct for circulation effects
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